U.S. · Hazmat · ERG
ERG guide number lookup.
Type a guide number to see what it covers, or pick a placard to see which guide the Emergency Response Guidebook starts you on.
In the 2024 Emergency Response Guidebook the orange guides run from 111 to 174, and the starting guide for a FLAMMABLE placard is Guide 127, for CORROSIVE Guide 153, and for DANGER or unknown contents Guide 111. Use a placard guide only until the ID number or shipping name is known, then use the guide listed for that material.
Guide or placard
Guide
How a guide number works
The Emergency Response Guidebook (ERG) is a guidebook for first responders during the initial phase of a transportation incident involving hazardous materials, and PHMSA hosts the 2024 edition. Its orange-bordered section holds one page pair for each guide, and the guide number is the link between a material and the response advice. In the 2024 edition the guides run from 111 to 174. Guides 121 and 167 are printed but marked "Intentionally left blank: There are no materials that refer to this guide." There is no guide 175 in this edition.
You normally reach a guide from an identification number. The ERG tells you to search for the four-digit UN or NA number in the yellow pages, or the material name in the blue pages, and read the guide number next to the entry. If the number is followed by a P, the material may suffer a violent polymerization. If the material is highlighted in green and is not on fire, the flowchart says to use Table 1 for isolation and protective action distances and to consult the orange guide. If it is on fire, use the orange guide for evacuation distances, then protect in the downwind direction according to Table 1 for any residual release. If the entry carries the reference for when spilled in water, consult Table 2 for the generated gases (for information only) and do not use water as the extinguishing agent. The flowchart carries a warning: do not use it if more than one hazardous material is involved. Call the emergency response agency listed inside the back cover instead.
When you only have a placard
The guidebook includes a table of markings, labels and placards for the case where the ID number or shipping name cannot be found. It says to use that table only then, to approach upwind, uphill and upstream at a safe distance, and to match the placard to the circled guide. Examples printed in the guidebook are Guide 127 for a FLAMMABLE (Class 3) placard and Guide 153 for a CORROSIVE (Class 8) placard. Guide 111 is the fallback when a DANGER or DANGEROUS placard is displayed, when the material is unknown, or when hazardous materials are suspected but no placards can be seen. The how-to flowchart also routes explosives placards: Guide 112 for Divisions 1.1, 1.2, 1.3 or 1.5 and Guide 114 for Divisions 1.4 or 1.6.
If multiple placards point to more than one guide, the ERG says to start with the most conservative guide, meaning the one that calls for the greatest protective action. Once the ID number or proper shipping name is known, you must switch to the more specific guide for that material.
All guide numbers in the 2024 edition
Titles are as printed in the orange section. Guides 111 to 128 cover the load types people meet most often: mixed loads, explosives, gases and flammable liquids.
Guides 111 to 139: mixed loads, explosives, gases, flammable liquids and solids, reactive substances
| Guide | Title |
|---|---|
| 111 | Mixed Load/Unidentified Cargo |
| 112 | Explosives - Division 1.1, 1.2, 1.3 or 1.5 |
| 113 | Flammable Materials (Wet/Desensitized Explosive) |
| 114 | Explosives - Division 1.4 or 1.6 |
| 115 | Gases - Flammable (Including Refrigerated Liquids) |
| 116 | Gases - Flammable (Unstable) |
| 117 | Gases - Toxic - Flammable (Extreme Hazard) |
| 118 | Gases - Flammable - Corrosive |
| 119 | Gases - Toxic - Flammable |
| 120 | Gases - Inert (Including Refrigerated Liquids) |
| 121 | Intentionally left blank: no materials refer to this guide |
| 122 | Gases - Oxidizing (Including Refrigerated Liquids) |
| 123 | Gases - Toxic |
| 124 | Gases - Toxic and/or Corrosive - Oxidizing |
| 125 | Gases - Toxic and/or Corrosive |
| 126 | Gases - Compressed or Liquefied (Including Refrigerant Gases) |
| 127 | Flammable Liquids (Water-Miscible) |
| 128 | Flammable Liquids (Water-Immiscible) |
| 129 | Flammable Liquids (Water-Miscible/Noxious) |
| 130 | Flammable Liquids (Water-Immiscible/Noxious) |
| 131 | Flammable Liquids - Toxic |
| 132 | Flammable Liquids - Corrosive |
| 133 | Flammable Solids |
| 134 | Flammable Solids - Toxic and/or Corrosive |
| 135 | Substances - Spontaneously Combustible |
| 136 | Substances - Spontaneously Combustible - Toxic and/or Corrosive (Air-Reactive) |
| 137 | Substances - Water-Reactive - Corrosive |
| 138 | Substances - Water-Reactive (Emitting Flammable Gases) |
| 139 | Substances - Water-Reactive (Emitting Flammable And Toxic Gases) |
Guides 140 to 174: oxidizers, organic peroxides, toxic substances, radioactive materials and others
| Guide | Title |
|---|---|
| 140 | Oxidizers |
| 141 | Oxidizers - Toxic |
| 142 | Oxidizers - Toxic (Liquid) |
| 143 | Oxidizers (Unstable) |
| 144 | Oxidizers (Water-Reactive) |
| 145 | Organic Peroxides (Heat and Contamination Sensitive) |
| 146 | Organic Peroxides (Heat, Contamination and Friction Sensitive) |
| 147 | Lithium Ion and Sodium Ion Batteries |
| 148 | Organic Peroxides (Heat and Contamination Sensitive/Temperature Controlled) |
| 149 | Substances (Self-Reactive) |
| 150 | Substances (Self-Reactive/Temperature Controlled) |
| 151 | Substances - Toxic (Non-Combustible) |
| 152 | Substances - Toxic (Combustible) |
| 153 | Substances - Toxic and/or Corrosive (Combustible) |
| 154 | Substances - Toxic and/or Corrosive (Non-Combustible) |
| 155 | Substances - Toxic and/or Corrosive (Flammable/Water-Sensitive) |
| 156 | Substances - Toxic and/or Corrosive (Combustible/Water-Sensitive) |
| 157 | Substances - Toxic and/or Corrosive (Non-Combustible/Water-Sensitive) |
| 158 | Infectious Substances |
| 159 | Substances (Irritating) |
| 160 | Halogenated Solvents |
| 161 | Radioactive Materials (Low Level Radiation) |
| 162 | Radioactive Materials (Low to Moderate Level Radiation) |
| 163 | Radioactive Materials (Low to High Level Radiation) |
| 164 | Radioactive Materials (Special Form/Low to High Level External Radiation) |
| 165 | Radioactive Materials (Fissile/Low to High Level Radiation) |
| 166 | Radioactive Materials - Corrosive (Uranium Hexafluoride/Water-Reactive) |
| 167 | Intentionally left blank: no materials refer to this guide |
| 168 | Carbon Monoxide (Refrigerated Liquid) |
| 169 | Aluminum (Molten) |
| 170 | Metals (Powders, Dusts, Shavings, Borings, Turnings, or Cuttings, etc.) |
| 171 | Substances (Low to Moderate Hazard) |
| 172 | Gallium and Mercury |
| 173 | Adsorbed Gases - Toxic |
| 174 | Adsorbed Gases - Flammable or Oxidizing |
Worked example
A tank trailer carries a red placard with the flame symbol and the number 3, and the driver is unconscious so there is no shipping paper to read. Match the FLAMMABLE placard in the placard table and you land on Guide 127. Open the orange section to Guide 127, titled Flammable Liquids (Water-Miscible), for the potential hazards, public safety, emergency response and first aid pages. The moment an ID number such as 1203 or a name such as gasoline is read from the panel, look it up in the yellow or blue pages: it points to its own guide, which may be Guide 128 for water-immiscible flammable liquids, and that guide replaces the placard guide.
What this page does not do
It does not list the ID number index. The yellow and blue pages are long two-column indexes, so use the guidebook itself or an official ERG app for a number-to-guide lookup. TNAADO already has a UN number lookup built on 49 CFR 172.101, but that table gives class, packing group and labels, not the ERG guide. We read the PHMSA PDF of the ERG 2024 through the Internet Archive copy captured on October 31, 2026 because the PHMSA server refused our automated request. In an emergency call 911 and the emergency response telephone number on the shipping paper first.
Sources
Sources opened and read November 2, 2026.
Frequently asked questions
What is an ERG guide number?
It is the three-digit number of an orange-bordered page pair in the Emergency Response Guidebook. Each guide gives potential hazards, public safety, evacuation, emergency response and first aid advice for a group of similar materials. In the 2024 edition the numbers run from 111 to 174.
How do I find the guide number for a UN number?
Look up the four-digit UN or NA identification number in the yellow pages of the ERG. The guide number is listed beside it. If you only have the name, use the blue pages. A P after the guide number means the material may polymerize violently.
What ERG guide is used for a flammable placard?
Guide 127 is the example the ERG gives for a FLAMMABLE (Class 3) placard. Use it only until the ID number or shipping name is known, then switch to the guide listed for that material.
Which ERG guide do I use when the material is unknown?
Guide 111 (Mixed Load/Unidentified Cargo). The ERG says to use it when a DANGER or DANGEROUS placard is displayed, when the nature of the material is not known, or when hazardous materials are suspected but no placards can be seen.
Are there guides that no material uses?
Yes. Guides 121 and 167 are printed in the 2024 edition marked "Intentionally left blank" with the note that no materials refer to them.
What does a green highlight in the ERG index mean?
The material has an entry in Table 1, initial isolation and protective action distances. If it is not on fire, the flowchart says to use Table 1 and consult the orange guide. If it is on fire, use the orange guide for evacuation distances, then protect downwind according to Table 1 for any residual release.
Is the ERG a substitute for training?
No. The guidebook itself states that first responders must be trained in its use and tells readers to become familiar with it before an emergency.
Not legal or compliance advice
This page is general information drawn from the sources listed, not legal, tax or compliance advice, and it is not run by any government agency. Rules, forms and dates change and your agency, base jurisdiction or enforcement officer decides your case, so confirm with the office named on this page before you rely on it. Everything runs in your browser; nothing you enter is sent anywhere.